Radiator cap should vent at 2 bar. If it vents above (or below) that, replace it. They are inexpensive.
If the water pump is pumping, and you are not getting flow through the radiator, make sure the thermostat is installed properly. When it is in the "cold" position, it blocks the flow from the radiator and opens the port in the head to allow coolant to circulate in the block only. When in the "hot" position, it plugs the port from the head and opens the feed from the radiator. If it is installed backwards, or it is installed with the oring on the wrong side, it may not properly block the flow from the head, and will thus run hot (circulating coolant from the engine instead of pulling from the cool side of the radiator).
If the water pump is pumping, and you are not getting flow through the radiator, make sure the thermostat is installed properly. When it is in the "cold" position, it blocks the flow from the radiator and opens the port in the head to allow coolant to circulate in the block only. When in the "hot" position, it plugs the port from the head and opens the feed from the radiator. If it is installed backwards, or it is installed with the oring on the wrong side, it may not properly block the flow from the head, and will thus run hot (circulating coolant from the engine instead of pulling from the cool side of the radiator).

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